The Synthesis, Reduction, and Decomposition of Novel High-nitrogen Bis S-triazinyl Hydrazines and Diazenes

The Synthesis, Reduction, and Decomposition of Novel High-nitrogen Bis S-triazinyl Hydrazines and Diazenes

4.11 - 1251 ratings - Source



Acid catalyzed nitration has been examined using a variety of novel nitration agents: guanidine nitrate, nitroguanidine, and ethylene glycol dinitrate. Reactions with activated or deactivated aromatics proceed rapidly and in high yield; however, regioselectivity was similar for all nitrating agents examined. The synthetic advantages of liquid EGDN include high solubility in organic solvents, strong nitration activity, and ease of preparation.Gas Chromatography Mass Spectrometry (GC/MS) Nitrogen Detection: An HP model 5890GC Series II equipped with an electronic pressure control system and a model 5971 electron- impact quadrupole MS was used for these studies. Manual tuning of the MS with perfluorotributylamine (PFTBA) was used to adjust relative abundance for m/z 69, m/z 100, and m/z 131 to 100, 15, and 45% +/- 1, anbsp;...


Title:The Synthesis, Reduction, and Decomposition of Novel High-nitrogen Bis S-triazinyl Hydrazines and Diazenes
Author: Jesse Stuart Moran
Publisher:ProQuest - 2008
ISBN-13:

You must register with us as either a Registered User before you can Download this Book. You'll be greeted by a simple sign-up page.

Once you have finished the sign-up process, you will be redirected to your download Book page.

How it works:
  • 1. Register a free 1 month Trial Account.
  • 2. Download as many books as you like (Personal use)
  • 3. Cancel the membership at any time if not satisfied.


Click button below to register and download Ebook
Privacy Policy | Contact | DMCA